OpenLDAP doesn't alter hosts resolution behavior.
As usual, the first address (A record) returned would be used.
That is to say, if "host ldap" returns 1.1.1.1, 2.2.2.2 and 3.3.3.3, will the OpenLDAP client library only connect to 1.1.1.1? If a connection to 1.1.1.1 fails, will it try 2.2.2.2 and then 3.3.3.3?
It will not try 2.2.2.2 or 3.3.3.3 automatically if a connection attempt
to 1.1.1.1 fails.
It might happen to try them on the next connection, if the host needs to
resolve the LDAP server's name again, and either 2.2.2.2 or 3.3.3.3 is
the first A record returned.